Metal nanoparticles on polymeric membranes applied in catalytic hydrogenations - IRD - Institut de recherche pour le développement
Chapitre D'ouvrage Année : 2025

Metal nanoparticles on polymeric membranes applied in catalytic hydrogenations

Résumé

Polymeric catalytic membranes, adapted for the immobilization of metal nanoparticles (MNPs) with the objective of being applied in hydrogenation reactions, are reviewed in this chapter, highlighting the works including a rational design and full characterization of the catalytic membrane reactors. The most relevant contributions concern zero-valent MNPs (mono-and bi-metallic systems) of late transition metals (groups 8-10), involving a significant variety of (un)functionalized polymers. Both batch and continuous flow processes are discussed, being of particular interest the latter ones for large-scale applications.

The literature analysis carried out evidences that there is still room for developing innovative polymeric catalytic membranes, regarding both design and applications. Thus, for instance, well-defined stereo-controlled polymeric membranes for enantioselective hydrogenations or multi-step processes involving a series of polymeric catalytic reactors would be of interest, particularly for production of fine chemicals under smooth conditions.

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Dates et versions

hal-04695506 , version 1 (12-09-2024)

Identifiants

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Rosa Pich, Jean-François Lahitte, Jean-Christophe Remigy, Daniel Pla, Montserrat Gómez. Metal nanoparticles on polymeric membranes applied in catalytic hydrogenations. Luis M. Martínez-Prieto. Surface Functionalized Metal Catalysts, Topics in Organometallic Chemistry, Springer, inPress, 978-3-031-73840-1. ⟨10.1007/3418_2024_120⟩. ⟨hal-04695506⟩
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